HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diisobutylaluminum hydride → 1-Benzofuran-5-ylmethanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diisobutylaluminum hydride | HCID 14487 | — |
| Reactant | Methyl 1-benzofuran-5-carboxylate | HCID 12674941 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 1-Benzofuran-5-ylmethanol | HCID 2795179 | — |
Reaction Steps
5.8 g (32.9 mmol) of methyl benzofuran-5-carboxylate are stirred analogously to Example 1 g in 50 ml of tetrahydrofuran with 64.5 ml (98.6 mmol) of DIBAL (1.53 molar) at -70° C. overnight.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04734407 |
| Source dataset | uspto-grants-1988_03 |
| ORD ID | ord-56d5422270d2469fa3a6d570c7cb9e7e |
| Source note | uspto-grants-1988_03 |