Methyl triflate → HCID 86742070, compound

Participants

Reaction Steps

10.65 g (0.03 mol) of N-p-toluenesulfonyldiphenylsulfilimine were suspended in 50 ml of dry toluene and, after addition of 6.55 g (0.04 mol) of methyl trifluoromethanesulfonate, were stirred under reflux for 2 hours. On cooling, the reaction solution divided into two phases, the lower of which was removed. The solid residue remaining on concentrating the lower phase was recrystallized from ethyl acetate and dried to give 11.0 g of the salt (I). Analysis and properties are indicated in Table 1.

Provenance & Evidence