Benzoyl Peroxide → 3-(1-Bromoethyl)benzophenone

HRID 570048Notes

Reaction equation

HRID 570048 reaction equation
[CH2:1]([C:3]1[CH:4]=[C:5]([CH:14]=[CH:15][CH:16]=1)[C:6]([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)=[O:7])[CH3:2].[Br:17]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[Br:17][CH:1]([C:3]1[CH:4]=[C:5]([CH:14]=[CH:15][CH:16]=1)[C:6]([C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1)=[O:7])[CH3:2]

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 5837303-Ethylbenzophenone

Product 1

HCID 128029243-(1-Bromoethyl)benzophenone

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

Into a 200 ml reactor equipped with a reflux condenser and a stirrer, 60 ml of carbon tetrachloride and 10 g of the above mentioned fraction containing 3-ethylbenzophenone were introduced. While stirring the resultant mixture at room temperature, 8.6 g of N-bromosuccinimide and 0.14 g of benzoyl peroxide were added thereto, and reflux was perfomed for 8 hours while stirring the reaction solution. After the reaction solution had been cooled to room temperature, the succinimide was filtered out, and carbon tetrachloride was distilled off from a filtrate under a reduced pressure. The spectrum data of the obtained product were in accord with those of 3-(1-bromoethyl)benzophenone.

Workup

  1. customInto a 200 ml reactor equipped with a reflux condenser and a stirrer
  2. additionwere introduced
  3. temperaturereflux
  4. filtrationthe succinimide was filtered out
  5. distillationcarbon tetrachloride was distilled off from a filtrate under a reduced pressure

Sources & evidence

ORD record
ord-cad028278be34bf88247a467fb14eca4
Source dataset
uspto-grants-1988_03
Patent number
US04734528

Reaction notes

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