Hydroxide → HCID 89541169, compound

HRID 575538Notes

Reaction equation

HRID 575538 reaction equation
[Br-].[CH2:2]([N+:14]1([CH3:20])[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]1)[CH2:3][CH2:4][CH2:5][CH2:6][N+:7]1([CH3:13])[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1.[Br-].[OH-:22]>>[OH-:22].[CH2:6]([N+:7]1([CH3:13])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12]1)[CH2:5][CH2:4][CH2:3][CH2:2][N+:14]1([CH3:20])[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]1.[OH-:22]

Participants

3

Reactant 2

HCID 961HydroxideHCID 1158951,1'-(Pentane-1,5-diyl)bis(1-methylpiperidin-1-ium) dibromide

Product 1

HCID 89541169HCID 89541169, compound

Procedure

1,1′-(pentane-1,5-diyl)bis(1-methylpiperidin-1-ium) bromide was subsequently converted to a hydroxide solution by column ion-exchange using an excess of MTO-DOWEX SBR LCNG(OH) resin. Distilled water was eluted through the column until the pH was less than 11 and the resulting solution concentrated to the desired concentration, typically ˜20 wt %. The concentration was confirmed by acid-base titration and by 1H NMR.

Workup

  1. washDistilled water was eluted through the column until the pH was less than 11
  2. concentrationthe resulting solution concentrated to the desired
  3. concentrationconcentration, typically ˜20 wt %
  4. concentrationThe concentration

Sources & evidence

ORD record
ord-1b6a819011c24d39bf5263a9ab2c1498
Source dataset
uspto-grants-2015_05
Patent number
US09035058B2

Reaction notes

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