Ammonia → HCID 867099, compound

HRID 578120Notes

Reaction equation

[OH:1][N:2]=[C:3]([NH2:10])[C:4]1[CH:9]=[CH:8][CH:7]=[N:6][CH:5]=1.[N+:11]([C:14]1[CH:15]=[C:16]([CH:20]=[CH:21][CH:22]=1)[C:17](Cl)=O)([O-:13])=[O:12].N>>[N+:11]([C:14]1[CH:15]=[C:16]([C:17]2[O:1][N:2]=[C:3]([C:4]3[CH:5]=[N:6][CH:7]=[CH:8][CH:9]=3)[N:10]=2)[CH:20]=[CH:21][CH:22]=1)([O-:13])=[O:12]

Participants

Reactant 3

HCID 222Ammonia

HCID 8495Benzoyl chloride, 3-nitro-

HCID 308113N-Hydroxynicotinimidamide

Product 1

HCID 867099HCID 867099, compound

Procedure

The title compound was prepared according to the procedure of Example 8 using N′-hydroxynicotinimidamide (Aldrich) and 3-nitrobenzoyl chloride (Aldrich). 1H NMR (300 MHz, CDCl3) δ 7.44-7.55 (m, 1H), 7.82 (t, J=8.3 Hz, 1H), 8.43-8.60 (m, 3H), 8.80 (dd, J=4.7, 1.7 Hz, 1H), 9.07-9.13 (m, 1H), 9.42 (d, J=2.0 Hz, 1H) ppm; MS (DCI/NH3) m/z 269 (M+H)+.

Sources & evidence

ORD record: ord-539a9c01ff494214b01baa73a2d6dc2d
Source dataset: uspto-grants-2015_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US09040568B2

Reaction notes

Loading…