Ammonia → HCID 11998321, compound

HRID 578132Notes

Reaction equation

HRID 578132 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([C:10]2[O:14][N:13]=[C:12]([C:15]3[CH:16]=[N:17][CH:18]=[CH:19][CH:20]=3)[N:11]=2)[CH:7]=[CH:8][CH:9]=1)([O-])=O.N>>[N:17]1[CH:18]=[CH:19][CH:20]=[C:15]([C:12]2[N:11]=[C:10]([C:6]3[CH:5]=[C:4]([CH:9]=[CH:8][CH:7]=3)[NH2:1])[O:14][N:13]=2)[CH:16]=1

Participants

3

Reactant 2

HCID 222AmmoniaHCID 867099HCID 867099, compound

Product 1

HCID 11998321HCID 11998321, compound

Procedure

The title compound was prepared according to the procedure of Example 46 using the product of Example 40. 1H NMR (300 MHz, DMSO-d6) δ ppm 5.60 (s, 2H), 6.84-6.93 (m, 1H), 7.24-7.33 (m, 2H), 7.41 (d, J=1.7 Hz, 1H), 7.60-7.67 (m, 1H), 8.38-8.45 (m, 1H), 8.81 (dd, J=5.1, 1.7 Hz, 1H), 9.23 (d, J=2.4 Hz, 1H) ppm; MS (DCI/NH3) m/z 239 (M+H)+, 256 (M+NH4)+.

Sources & evidence

ORD record
ord-396dccc881754eaf95ab6365c25f8d3d
Source dataset
uspto-grants-2015_05
Patent number
US09040568B2

Reaction notes

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