HCID 54122748, compound → HCID 54254275, compound

HRID 579764Notes

Reaction equation

HRID 579764 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8]=[C:9]([N:16]2[CH:20]=[N:19][CH:18]=[N:17]2)[C:10]([C:12]2([CH3:15])[CH2:14][CH2:13]2)=[O:11])=[CH:4][CH:3]=1.N1C=CN=N1>>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8]=[C:9]([N:16]2[CH:20]=[N:19][CH:18]=[N:17]2)[CH:10]([C:12]2([CH3:15])[CH2:14][CH2:13]2)[OH:11])=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 54122748HCID 54122748, compoundHCID 178418936HCID 178418936, compound2×

Product 1

HCID 54254275HCID 54254275, compound

Procedure

The NMR spectrum of the starting material, II-B isomer of 3-(4-chlorophenyl)-1-(1-methylcyclopropyl)-2-(1,2,4-triazole-1-yl)-2-propene-1-one, is as follows: 8.12 (1H, s, triazole proton), 8.03 (1H, s, triazole proton), 7.55 (1H, s, olefin proton), 7.21 (2H, d, phenyl proton, J=8 Hz), 6.81 (2H, d, phenyl proton, J=8 Hz), 1.50-1.25 (2H, m, methylene proton of cyclopropyl group), 1.28 (3H, s, methyl proton), 0.90-0.65 (2H, m, methylene proton of cyclopropyl group).

Sources & evidence

ORD record
ord-a759db71499548939ef972853c2aaf6f
Source dataset
uspto-grants-1988_06
Patent number
US04749716

Reaction notes

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