HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → Tris(2-chloroethyl) phosphite
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Ethylene Oxide | HCID 6354 | — |
| Reactant | Phosphorus trichloride | HCID 24387 | — |
| Reactant | Bis(2-chloroethyl) P-(2-chloroethyl)phosphonate | HCID 80518 | — |
| Product | Tris(2-chloroethyl) phosphite | HCID 8783 | — |
| Product | Phosphonic dichloride, ethenyl- | HCID 74035 | — |
Reaction Steps
Tris-(2-chloroethyl) phosphite is prepared from phosphorus trichloride and ethylene oxide, and bis(2-chloroethyl) 2-chloroethanephosphonate, inter alia, is formed therefrom by Arbusov rearrangement. After phosgenation and splitting off of hydrogen chloride by means of heat, vinylphosphonic acid dichloride results, which, after purification by distillation, is hydrolyzed with water to give pure vinylphosphonic acid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04749758 |
| Source dataset | uspto-grants-1988_06 |
| ORD ID | ord-3418be5aea174ca3be6d10d7b2f74b87 |
| Source note | uspto-grants-1988_06 |