Metaperiodic acid → HCID 20135720, compound

HRID 580026Notes

Reaction equation

HRID 580026 reaction equation
[C:1]([O:10][CH2:11][C:12]([Cl:14])=[CH2:13])(=[O:9])[CH:2](C(C([O-])=O)O)[OH:3].I(O)(=O)(=O)=O>C(OCC)C>[OH2:3].[C:1]([O:10][CH2:11][C:12]([Cl:14])=[CH2:13])(=[O:9])[CH:2]=[O:3]

Participants

4

Reactant 2

HCID 65185Metaperiodic acidHCID 20135715HCID 20135715, compound

Product 1

HCID 20135720HCID 20135720, compoundYield 333.4%

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

To a solution of 6.3 g (0.021 mole) 2-chloroallyl tartarate in 300 ml ethyl ether was added 5.02 g (0.022 mole) periodic acid and the mixture was stirred for two hours at room temperature. The mixture was filtered and the filtrate evaporated to afford 5.83 g (83%) of the title compound.

Workup

  1. filtrationThe mixture was filtered
  2. customthe filtrate evaporated

Sources & evidence

ORD record
ord-172d59195ca84b65b312cbb7f868d1cd
Source dataset
uspto-grants-1988_06
Patent number
US04751297

Reaction notes

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