Sodium Methoxide → HCID 13803748, compound

HRID 580071Notes

Reaction equation

HRID 580071 reaction equation
[CH3:1][O:2][C:3]([CH2:5][S:6][C:7]1[CH:18]=[C:17]([CH3:19])[CH:16]=[CH:15][C:8]=1[O:9][CH2:10][C:11](OC)=[O:12])=[O:4].C[O-].[Na+]>>[CH3:19][C:17]1[CH:16]=[CH:15][C:8]2[O:9][CH2:10][C:11](=[O:12])[CH:5]([C:3]([O:2][CH3:1])=[O:4])[S:6][C:7]=2[CH:18]=1

Participants

3

Reactant 2

HCID 10942334Sodium MethoxideHCID 13536201HCID 13536201, compound

Product 1

HCID 13803748HCID 13803748, compoundYield 73.4%

Procedure

Methyl 2-methoxycarbonylmethylthio-4-methylphenoxyacetate (8.9 g) is treated with sodium methoxide in the same manner as described in Reference Example 2 to give methyl 7-methyl-3-oxo-3,4-dihydro-2H-1,5-benzoxathiepin-4-carboxylate (5.8 g) as a colorless oil.

Sources & evidence

ORD record
ord-4c4c04f1e8624ca3b5938b90cd01af30
Source dataset
uspto-grants-1988_06
Patent number
US04751316

Reaction notes

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