HCID 53859634, compound → HCID 53920932, compound

HRID 580970Notes

Reaction equation

HRID 580970 reaction equation
[CH2:1]([C:4]1[CH:5]=[C:6]([CH2:18][CH2:19][C:20]([O:22][CH2:23]C)=O)[CH:7]=[CH:8][C:9]=1[O:10][S:11]([C:14]([F:17])([F:16])[F:15])(=[O:13])=[O:12])[CH:2]=[CH2:3].C(C1C=C(O)C=CC=1CCCOC)C=C>>[F:16][C:14]([F:15])([F:17])[S:11]([O:10][C:9]1[CH:8]=[CH:7][C:6]([CH2:18][CH2:19][CH2:20][O:22][CH3:23])=[CH:5][C:4]=1[CH2:1][CH:2]=[CH2:3])(=[O:12])=[O:13]

Participants

3

Reactant 2

HCID 53859634HCID 53859634, compoundHCID 54564898HCID 54564898, compound

Product 1

HCID 53920932HCID 53920932, compound

Procedure

Using a similar procedure to that described in Example 1 for the preparation of ethyl 3-(3-allyl-4-trifluoromethylsulphonyloxyphenyl)propionate but using 3-(2-allyl-4-hydroxyphenyl)-1-methoxypropane as starting material there was obtained 2-allyl-4-(3-methoxypropyl)phenyl trifluoromethane sulphonate as a colourless oil; NMR(CDCl3): 1.8-1.95(2H,m), 2.65-2.75(2H,t), 3.3-3.5(7H,m), 5.05-5.2(2H,m), 5.8-6.0(1H,m) and 7.0-7.3(3H,m).

Sources & evidence

ORD record
ord-9bc4e49713c243849842d7e41db28185
Source dataset
uspto-grants-1999_07
Patent number
US05919793

Reaction notes

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