Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Methane | HCID 297 | — |
| Reactant | Styrene | HCID 7501 | — |
| Reactant | Bromobenzene | HCID 7961 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Catalyst | Tetrabutylammonium Acetate | HCID 82707 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | Stilbene | HCID 11502 | 74.1% |
Reaction Steps
In a miniautoclave, 85 mg of palladium on active charcoal (similar to Example 59, metal content 5%) are suspended in 20 ml of DMF. After 2 mmol of bromobenzene, 2 mmol of styrene, and 4 mmol of tetrabutylammonium acetate have been added, heating at 120° C. is performed with shaking. After 16 h, 267 mg of stilbene can be isolated from the reaction solution. This corresponds to a 74% conversion.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US05925463 |
|---|
| Source dataset | uspto-grants-1999_07 |
|---|
| ORD ID | ord-73a61900dc084335aa391226e4f2b84a |
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| Source note | uspto-grants-1999_07 |
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