HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 582889Generated: October 30, 2026
Sulfuryl chloride → Decanoic acid, 3-oxo-, methyl ester
https://huagongshe.com/reaction/582889
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Sulfuryl chloride | HCID 24648 | — |
| Reactant | Decanoic acid, 3-oxo-, methyl ester | HCID 89669 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | Decanoic acid, 3-oxo-, methyl ester | HCID 89669 | — |
| Product | Methyl 2-chloro-3-oxodecanoate | HCID 54424532 | — |
Reaction Steps
In 500 ml of toluene was dissolved 160 g (0.8 mol) of the resulting methyl 3-oxodecanoate, the solution was cooled to 0 to 5° C., and 108 g (0.8 mol) of sulfuryl chloride was added thereto dropwise, followed by stirring at room temperature overnight. Toluene was removed by evaporation to give 187.8 g (0.8 mol; yield: 100% from methyl 3-oxodecanoate) of the title compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US05925792 |
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| Source dataset | uspto-grants-1999_07 |
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| ORD ID | ord-7e39e4aa2d094d64af5bcc76a6c1c8f7 |
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| Source note | uspto-grants-1999_07 |
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