1,4-Dibromobutane → HCID 53971247, compound

HRID 583340Notes

Reaction equation

HRID 583340 reaction equation
[CH3:1][O:2][C:3](=[O:23])[C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([OH:10])[C:5]=1[NH:11][S:12]([C:15]1[CH:20]=[CH:19][C:18]([O:21][CH3:22])=[CH:17][CH:16]=1)(=[O:14])=[O:13].Br[CH2:25][CH2:26][CH2:27][CH2:28]Br>>[CH3:1][O:2][C:3]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]2[O:10][CH2:28][CH2:27][CH2:26][CH2:25][N:11]([S:12]([C:15]3[CH:16]=[CH:17][C:18]([O:21][CH3:22])=[CH:19][CH:20]=3)(=[O:13])=[O:14])[C:5]=12)=[O:23]

Participants

3

Reactant 2

HCID 80561,4-DibromobutaneHCID 54048961HCID 54048961, compound

Product 1

HCID 53971247HCID 53971247, compoundYield 30%

Procedure

In the same manner as described in Example 159, 0.400 g (1.187 mmol) of the product of Example 31 and 0.198 mL (1.662 mmol) of 1,4-dibromobutane provided 0.139 g (30%) of the desired product as a white solid. Electrospray Mass Spec: 392 (M+H).

Sources & evidence

ORD record
ord-aac6af0fa50341e9b2e9faa8d3651798
Source dataset
uspto-grants-1999_07
Patent number
US05929097

Reaction notes

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