3-(Tributylstannyl)pyridine → HCID 70054774, compound

HRID 583375Notes

Reaction equation

HRID 583375 reaction equation
[CH3:1][O:2][C:3](=[O:31])[C:4]1[CH:9]=[C:8](Br)[CH:7]=[C:6]([CH3:11])[C:5]=1[N:12]([S:20]([C:23]1[CH:28]=[CH:27][C:26]([O:29][CH3:30])=[CH:25][CH:24]=1)(=[O:22])=[O:21])[CH2:13][C:14]1[CH:15]=[N:16][CH:17]=[CH:18][CH:19]=1.C([Sn](CCCC)(CCCC)[C:37]1[CH:38]=[N:39][CH:40]=[CH:41][CH:42]=1)CCC>>[CH3:1][O:2][C:3](=[O:31])[C:4]1[CH:9]=[C:8]([C:37]2[CH:38]=[N:39][CH:40]=[CH:41][CH:42]=2)[CH:7]=[C:6]([CH3:11])[C:5]=1[N:12]([S:20]([C:23]1[CH:28]=[CH:27][C:26]([O:29][CH3:30])=[CH:25][CH:24]=1)(=[O:22])=[O:21])[CH2:13][C:14]1[CH:15]=[N:16][CH:17]=[CH:18][CH:19]=1

Participants

3

Reactant 2

HCID 34838483-(Tributylstannyl)pyridineHCID 70053864HCID 70053864, compound

Product 1

HCID 70054774HCID 70054774, compoundYield 87%

Procedure

In the same manner as described in Example 139, 505 mg (1.0 mmol) of the product of Example 89 and 515 mg (1.4 mmol) of 3-(tributylstannyl)pyridine provided 437 mg (87%) of the desired product as a pale yellow solid. Electrospray Mass Spec 504 (M+H).

Sources & evidence

ORD record
ord-f53b0548b1344a159f6f05f1ca705459
Source dataset
uspto-grants-1999_07
Patent number
US05929097

Reaction notes

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