Toluene → HCID 21311168, compound

HRID 583641Notes

Reaction equation

HRID 583641 reaction equation
[CH:1]([C:3]1([OH:13])[CH2:8][CH2:7][CH:6]([C:9](C)(C)C)[CH2:5][CH2:4]1)=[CH2:2].[C:14]1(C)C=CC=C[CH:15]=1>>[CH:1]([C:3]([OH:13])([CH2:8][CH2:7][CH2:14][CH3:15])[CH2:4][CH2:5][CH2:6][CH3:9])=[CH2:2]

Participants

3

Reactant 2

HCID 1140TolueneHCID 11769186HCID 11769186, compound

Product 1

HCID 21311168HCID 21311168, compound

Procedure

A solution of 2.0 grams of 1-vinyl-4-tert-butylcyclohexanol in 30 ml of toluene containing 40 mg of MTO was refluxed 4 hrs. TLC analysis indicated the presence of some residual starting material, so an additional 10 mg of MTO was added and reflux continued until the starting material was consumed. Workup as in the case of 5-vinyl-5-nonanol above gave 1.25 g (69%) of product as a colorless liquid, bp 90 deg C./15 mm Hg. NMR spectrum was consistent with that expected for the product.

Workup

  1. additionso an additional 10 mg of MTO was added
  2. temperaturereflux
  3. customwas consumed

Sources & evidence

ORD record
ord-f6dab9b1d7234e3281b54c950087ed7b
Source dataset
uspto-grants-1999_07
Patent number
US05929298

Reaction notes

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