1-Bromooctadecane → HCID 10404166, compound

HRID 583955Notes

Reaction equation

HRID 583955 reaction equation
CC/C=C\C/C=C\C/C=C\CCCCCCCCO.[CH2:20]([Br:38])[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37]>>[Br:38][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27]/[CH:28]=[CH:29]\[CH2:30]/[CH:31]=[CH:32]\[CH2:33]/[CH:34]=[CH:35]\[CH2:36][CH3:37]

Participants

3

Reactant 2

HCID 82181-BromooctadecaneHCID 6436081(9Z,12Z,15Z)-9,12,15-Octadecatrien-1-ol

Product 1

HCID 10404166HCID 10404166, compoundYield 93%

Procedure

From linolenyl alcohol (1c) (102 mg, 0.39 mmol), using the procedure described above for preparation of 1-bromooctadecane (2a), (Z,Z,Z)-1-bromo-9,12,15-octadecatriene (2c) (118 mg, 93%) was obtained as a colourless oil.

Sources & evidence

ORD record
ord-3f02f90dbdc84e0faa2bd880897acdf0
Source dataset
uspto-grants-2005_08
Patent number
US06924309B2

Reaction notes

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