1-Bromooctadecane → HCID 58559582, compound

HRID 583956Notes

Reaction equation

C(O)CCCC/C=C\C/C=C\C/C=C\CCCCC.[CH2:20]([Br:38])[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37]>>[Br:38][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24]/[CH:25]=[CH:26]\[CH2:27]/[CH:28]=[CH:29]\[CH2:30]/[CH:31]=[CH:32]\[CH2:33][CH2:34][CH2:35][CH2:36][CH3:37]

Participants

Reactant 2

HCID 82181-Bromooctadecane

HCID 9795274gamma-Linolenyl alcohol

Product 1

HCID 58559582HCID 58559582, compoundYield 96%

Procedure

From gamma linolenyl alcohol (1d) (143 mg, 0.54 mmol), using the procedure described above for preparation of 1-bromooctadecane (2a), (Z,Z,Z)-1-bromo-6,9,12-octadeca-triene (2d) (170 mg, 96%) was obtained as a colourless oil.

Sources & evidence

ORD record: ord-6a74efbc7e0c4effa347020430f1f98d
Source dataset: uspto-grants-2005_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06924309B2

Reaction notes

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