1-Bromooctadecane → HCID 86759790, compound

HRID 583957Notes

Reaction equation

HRID 583957 reaction equation
[CH:1](O)=[CH:2][CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=[CH:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22].C([Br:42])CCCCCCCCCCCCCCCCC>>[Br:42][CH2:22][CH2:21][CH2:20]/[CH:19]=[CH:18]\[CH2:17][CH:16]=[CH:15][CH2:14][CH:13]=[CH:12][CH2:11][CH:10]=[CH:9][CH2:8][CH:7]=[CH:6][CH2:5][CH:4]=[CH:3][CH2:2][CH3:1]

Participants

3

Reactant 2

HCID 82181-BromooctadecaneHCID 71338604Docosa-1,3,5,7,9,11-hexaen-1-ol

Product 1

HCID 86759790HCID 86759790, compoundYield 92%

Procedure

From docosahexaenyl alcohol 1e (201 mg, 0.64 mmol), using the procedure described above for preparation of 1-bromooctadecane (2a), (all-Z)-1-bromo-4,7,10,13,16,19-docosahexaene (2e) (221 mg, 92%) was obtained as a colourless oil.

Sources & evidence

ORD record
ord-4ffee0bc49234aaeb3681d0f3f277d82
Source dataset
uspto-grants-2005_08
Patent number
US06924309B2

Reaction notes

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