HRID584337

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：Fc1c(F)c(F)c([SiH](OCCCl)c2c(F)c(F)c(F)c(F)c2F)c(F)c1F

HCID131724616

未命名化合物

HCID178419089

未命名化合物

PRODUCTS

生成物

结构：CCO[Si](c1c(F)c(F)c(F)c(F)c1F)(c1c(F)c(F)c(F)c(F)c1F)c1c(F)c(F)c(F)c(F)c1F

HCID23523565

Ethoxy[tris(pentafluorophenyl)]silane

C20H5F15OSi

结构：Fc1c(F)c(F)c(C(CO[SiH3])(c2c(F)c(F)c(F)c(F)c2F)c2c(F)c(F)c(F)c(F)c2F)c(F)c1F

HCID131724617

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID3283

Diethyl Ether

C4H10O

2 次

PROCEDURE

实验过程

88.54 g (0.200 mol) of di(pentafluorophenyl)chloroethoxysilane in Et2O is slowly added to solution of C6F5—Li (0.200 mol, 34.80 g, prepared in situ) in Et2O at −78° C. The solution is stirred for over night allowing it to warm up to room temperature. Formed clear solution is filtered and evaporated to dryness to result tri(pentafluorophenyl)ethoxysilane, (C6F5)3SiOEt.

WORKUP

后处理

customFormed clear solution
filtrationis filtered
customevaporated to dryness

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-2c39385c3ecc4e6a932e9cf646c534fc
来源数据集: uspto-grants-2005_08
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06924384B2
来源说明: uspto-grants-2005_08

反应 SMILES

[F:1][C:2]1[C:7]([SiH:8]([C:13]2[C:18]([F:19])=[C:17]([F:20])[C:16]([F:21])=[C:15]([F:22])[C:14]=2[F:23])[O:9][CH2:10][CH2:11]Cl)=[C:6]([F:24])[C:5]([F:25])=[C:4]([F:26])[C:3]=1[F:27].[C:28]1([Li])[C:37]([F:38])=[C:35]([F:36])[C:33]([F:34])=[C:31]([F:32])[C:29]=1[F:30]>CCOCC>[F:38][C:37]1[C:28]([C:11]([C:13]2[C:14]([F:23])=[C:15]([F:22])[C:16]([F:21])=[C:17]([F:20])[C:18]=2[F:19])([C:28]2[C:37]([F:38])=[C:35]([F:36])[C:33]([F:34])=[C:31]([F:32])[C:29]=2[F:30])[CH2:10][O:9][SiH3:8])=[C:29]([F:30])[C:31]([F:32])=[C:33]([F:34])[C:35]=1[F:36].[Si:8]([O:9][CH2:10][CH3:11])([C:28]1[C:29]([F:30])=[C:31]([F:32])[C:33]([F:34])=[C:35]([F:36])[C:37]=1[F:38])([C:13]1[C:18]([F:19])=[C:17]([F:20])[C:16]([F:21])=[C:15]([F:22])[C:14]=1[F:23])[C:7]1[C:6]([F:24])=[C:5]([F:25])[C:4]([F:26])=[C:3]([F:27])[C:2]=1[F:1]