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HRID586491

反应详情

EQUATION

反应方程式

HRID 586491 的结构方程式

REACTANTS

反应物

2
结构：Cc1c(I)c(=O)n(C2CCCC2)c2nc(S(C)=O)ncc12
HCID11212220

8-Cyclopentyl-6-iodo-2-methanesulfinyl-5-methyl-8H-pyrido[2,3-d]pyrimidin-7-one

C14H16IN3O2S

结构：CSc1ncc2c(C)c(Br)c(=O)n(C3CCCC3)c2n1
HCID11739693

6-Bromo-8-cyclopentyl-5-methyl-2-methylsulfanyl-8H-pyrido[2,3-d]pyrimidin-7-one

C14H16BrN3OS

PRODUCTS

生成物

1
结构：Cc1c(Br)c(=O)n(C2CCCC2)c2nc(S(C)=O)ncc12
HCID11372127

未命名化合物

PROCEDURE

实验过程

Prepared from 6-bromo-8-cyclopentyl-5-methyl-2-methylsulfanyl-8H-pyrido[2,3-d]pyrimidin-7-one following the procedure described for 8-cyclopentyl-6-iodo-2-methanesulfinyl-5-methyl-8H-pyrido[2,3-d]pyrimidin-7-one. MS (APCI) Calc'd for C14H16BrN3O2S: 371.01, 369.01. Found: 372.9 (M+1), 371.9. 1H NMR δ (400 MHz, CDCl3) 9.01 (s, 1H), 6.06-5.97 (m, 1H), 2.93 (s, 3H), 2.67 (s, 3H), 2.21-2.11 (m, 2H), 2.10-2.04 (m, 2H), 1.94-1.87 (m, 2H), 1.67-1.62 (m, 2H).