HCID 86595796, compound → HCID 86595802, compound

HRID 586657Notes

Reaction equation

HRID 586657 reaction equation
[CH3:1][O:2][CH2:3][C@@H:4]1[C@H:6]([CH:7]=[O:8])[C@:5]1([CH3:23])[C:9]1[CH:18]=[CH:17][C:16]2[C:15]([CH3:20])([CH3:19])[CH2:14][CH2:13][C:12]([CH3:22])([CH3:21])[C:11]=2[CH:10]=1.CC12C(C)(C)C(C(OC[C@@H]3[C@H](COC)[C@]3(C)C3C=CC4C(C)(C)CCC(C)(C)C=4C=3)=O)(CC1)OC2=O>>[CH3:1][O:2][CH2:3][C@H:4]1[C@@H:6]([CH:7]=[O:8])[C@@:5]1([CH3:23])[C:9]1[CH:18]=[CH:17][C:16]2[C:15]([CH3:20])([CH3:19])[CH2:14][CH2:13][C:12]([CH3:22])([CH3:21])[C:11]=2[CH:10]=1

Participants

3

Reactant 2

HCID 86595796HCID 86595796, compoundHCID 86595801HCID 86595801, compound

Product 1

HCID 86595802HCID 86595802, compoundYield 99%

Procedure

Following a procedure similar to that for the preparation of Intermediate 12a but using Intermediate 9a as the starting material afforded the title compound (42 mg, 99% yield) as a colorless oil:

Sources & evidence

ORD record
ord-4a10649b0b754b2682ec26e32b28b6e0
Source dataset
uspto-grants-2005_08
Patent number
US06936636B2

Reaction notes

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