12318-21-7 → HCID 131734461, compound

HRID 589270Notes

Reaction equation

HRID 589270 reaction equation
[CH-:1]1[CH:5]=[CH:4][CH:3]=[CH:2]1.[CH-:6]1[CH:10]=[CH:9][CH:8]=[CH:7]1.[Rh+2:11].[CH3:12][CH:13]([Si:15]([CH:55]([CH3:57])[CH3:56])([CH:52]([CH3:54])[CH3:53])[C:16]#[C:17][C:18]1[C:39]2[C:30](=[CH:31][C:32]3[C:37]([CH:38]=2)=[CH:36][CH:35]=[CH:34][CH:33]=3)[C:29]([C:40]#[C:41][Si:42]([CH:49]([CH3:51])[CH3:50])([CH:46]([CH3:48])[CH3:47])[CH:43]([CH3:45])[CH3:44])=[C:28]2[C:19]=1[CH:20]=[C:21]1[C:26](=[CH:27]2)[CH:25]=[CH:24][CH:23]=[CH:22]1)[CH3:14]>ClC1C=CC=CC=1>[CH-:1]1[CH:5]=[CH:4][CH:3]=[CH:2]1.[CH-:6]1[CH:10]=[CH:9][CH:8]=[CH:7]1.[Rh+2:11].[CH3:48][CH:46]([Si:42]([CH:49]([CH3:51])[CH3:50])([CH:43]([CH3:45])[CH3:44])[C:41]#[C:40][C:29]1[C:28]2[C:19](=[CH:20][C:21]3[C:26]([CH:27]=2)=[CH:25][CH:24]=[CH:23][CH:22]=3)[C:18]([C:17]#[C:16][Si:15]([CH:52]([CH3:54])[CH3:53])([CH:13]([CH3:14])[CH3:12])[CH:55]([CH3:56])[CH3:57])=[C:39]2[C:30]=1[CH:31]=[C:32]1[C:37](=[CH:38]2)[CH:36]=[CH:35][CH:34]=[CH:33]1)[CH3:47]

Participants

4

Reactant 2

HCID 308202212318-21-72×HCID 15530606[Pentacene-6,13-diyldi(ethyne-2,1-diyl)]bis[tri(propan-2-yl)silane]

Product 1

HCID 131734461HCID 131734461, compound

Reagents, catalysts & solvents 1

HCID 7964ChlorobenzeneSolvent2×

Procedure

Film conductivity studies of rhodocene doped TIPS-pentacene were carried out as follows. 0.5 mg of rhodocene dimer and 11 mg TIPS-pentacene were mixed in 0.6 ml of chlorobenzene in an N2 glove box, and thoroughly stirred at room temperature for 2 hours to completely dissolve the materials, to produce a 5 wt % solution of the rhodocene/TIPS-pentacene in chlorobenzene. Quartz glass substrates patterned with inter-digitated Au electrodes with 150 [tin spacings (see description above]), The undoped and doped films were formed by drop-casting the solution of pure TIPS-pentacene or the co-solution (with dopant) in a N2 box onto the substrates that were heated to 90° C., followed by post-annealing at the same temperature for 5 min. Electrical characteristics of the resulting simple devices were measured in the glove box by connecting a two point probe station to the gold electrodes of the devices.

Workup

  1. dissolutionto completely dissolve the materials

Sources & evidence

ORD record
ord-53ed1d017ae0474b9488ad64c1b5b7de
Source dataset
uspto-grants-2016_01
Patent number
US09231219B2

Reaction notes

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