Sodium Hydroxide → HCID 86730874, compound

HRID 589277Notes

Reaction equation

HRID 589277 reaction equation
F[B-](F)(F)F.[CH3:6][N+:7]1[C:11](SC(C)CC)=[N:10][N:9]([CH:17]([CH3:20])[CH2:18][CH3:19])[N:8]=1.[OH-:21].[Na+]>O>[CH3:6][N+:7]1[C:11]([O-:21])=[N:10][N:9]([CH:17]([CH3:20])[CH2:18][CH3:19])[N:8]=1

Participants

4

Reactant 2

HCID 14798Sodium Hydroxide2×HCID 86730870HCID 86730870, compound

Product 1

HCID 86730874HCID 86730874, compoundYield 100%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Thus, 1-methyl-3-(1-methylpropyl)-5-(1-methylpropylthio)tetrazolium tetrafluoroborate (137 mg, 0.43 mmol) was introduced into a recovery flask; an aqueous sodium hydroxide solution (prepared by the dissolution of sodium hydroxide (24 mg, 0.60 mmol) in water (10 mL)) was added to the recovery flask; and stirring was carried out for 30 minutes. Extraction with methylene chloride, drying over anhydrous sodium sulfate, and distillation of the solvent yielded 1-methyl-3-(1-methylpropyl)tetrazolium-5-olate (yield=65 mg, 100%).

Workup

  1. additionwas added to the recovery flask
  2. extractionExtraction with methylene chloride
  3. dry with materialdrying over anhydrous sodium sulfate, and distillation of the solvent

Sources & evidence

ORD record
ord-5fc2e3ce95f940efa626267e4bdeb208
Source dataset
uspto-grants-2016_01
Patent number
US09231278B2

Reaction notes

Loading…