HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethyl phosphite → (4-Pentenyl)phosphonic acid diethyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethyl phosphite | HCID 31215 | — |
| Reactant | 1-Pentene, 5-bromo- | HCID 70704 | — |
| Product | (4-Pentenyl)phosphonic acid diethyl ester | HCID 13462469 | — |
Reaction Steps
5-bromo-1-pentene was combined with triethylphosphite in the absence of solvent using microwave conditions at 150° C. to give diethyl 4-pentenylphosphonate. Diethyl 4-pentenylphosphonate was combined with bromotrimethyl silane and subsequently quenched with methanol to afford diethyl 4-pentenylphosphonic acid according to Scheme 8.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09234985B2 |
| Source dataset | uspto-grants-2016_01 |
| ORD ID | ord-698695d1b33f449b8bdad4e1c0e8db68 |
| Source note | uspto-grants-2016_01 |