참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | Bis(3-chloro-2-hydroxypropyl)sulfide | HCID 19980843 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | 2,2'-(Thiobis(methylene))bis(oxirane) | HCID 203672 | 95% |
반응 단계
Next, bis(3-chloro-2-hydroxypropyl)sulfide described above was dripped into a reaction vessel containing a mixed solvent consisting of 410 g of toluene and 260 g of 32% aqueous solution of sodium hydroxide with the temperature of the solution in the reaction vessel being maintained at 0 to 10° C. At the point of the completion, no scum-like insoluble matter was generated. The aqueous layer was removed, and the organic layer was washed with 180 g of water three times. After that, no scum-like insoluble matter was generated. After that, the solvent was distilled away, thereby obtaining 138 g (total yield: 95%) of bis(β-epoxypropyl)sulfide (the compound represented by formula (2) above).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US09242947B2 |
|---|
| 출처 데이터셋 | uspto-grants-2016_01 |
|---|
| ORD ID | ord-f8d17358a8a04948aa97e14c4fb8c5cf |
|---|
| 출처 메모 | uspto-grants-2016_01 |
|---|