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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 593313생성일: 2026년 10월 25일

Sodium Hydroxide → 2,2'-(Thiobis(methylene))bis(oxirane)

https://huagongshe.com/reaction/593313

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참여 물질

역할이름HCID투입량
반응물Sodium HydroxideHCID 14798—
반응물Bis(3-chloro-2-hydroxypropyl)sulfideHCID 19980843—
용매TolueneHCID 1140—
생성물2,2'-(Thiobis(methylene))bis(oxirane)HCID 20367295%

반응 조건

온도5 °C

반응 단계

Next, bis(3-chloro-2-hydroxypropyl)sulfide described above was dripped into a reaction vessel containing a mixed solvent consisting of 410 g of toluene and 260 g of 32% aqueous solution of sodium hydroxide with the temperature of the solution in the reaction vessel being maintained at 0 to 10° C. At the point of the completion, no scum-like insoluble matter was generated. The aqueous layer was removed, and the organic layer was washed with 180 g of water three times. After that, no scum-like insoluble matter was generated. After that, the solvent was distilled away, thereby obtaining 138 g (total yield: 95%) of bis(β-epoxypropyl)sulfide (the compound represented by formula (2) above).

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US09242947B2
출처 데이터셋uspto-grants-2016_01
ORD IDord-f8d17358a8a04948aa97e14c4fb8c5cf
출처 메모uspto-grants-2016_01