HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 593314Generated: October 26, 2026
Hydrogen Sulfide → Bis(3-chloro-2-hydroxypropyl)sulfide
https://huagongshe.com/reaction/593314
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Hydrogen Sulfide | HCID 402 | — |
| Reactant | Water | HCID 962 | — |
| Reactant | Epichlorohydrin | HCID 7835 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | Bis(3-chloro-2-hydroxypropyl)sulfide | HCID 19980843 | 96% |
Reaction Steps
185 g (2.0 mol) of epichlorohydrin, 30 g of water, 5 g of methanol and 1.5 g of 32% aqueous solution of sodium hydroxide were mixed together, and 35 g (1.0 mol) of hydrogen sulfide was blown into the mixture with stirring with the temperature of the solution being maintained at 5 to 15° C., thereby obtaining 210 g (0.96 mol, yield: 96%) of bis(3-chloro-2-hydroxypropyl)sulfide.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US09242947B2 |
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| Source dataset | uspto-grants-2016_01 |
|---|
| ORD ID | ord-6f5614cbc141486288a11870c4615d97 |
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| Source note | uspto-grants-2016_01 |
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