Benzyl Chloride → HCID 70635363, compound

HRID 596429Notes

Reaction equation

HRID 596429 reaction equation
[Cl-].[C:2]1([N+:8]2[C:13]([SH:14])=[CH:12][C:11]([NH2:15])=[CH:10][N:9]=2)[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:16]([Cl:23])[C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1>C1(C)C=CC=CC=1>[Cl-:23].[C:2]1([N+:8]2[C:13]([S:14][CH2:16][C:17]3[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=3)=[CH:12][C:11]([NH2:15])=[CH:10][N:9]=2)[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

4

Reactant 2

HCID 7503Benzyl ChlorideHCID 178508063HCID 178508063, compound

Product 1

HCID 70635363HCID 70635363, compoundYield 90.2%

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

5 parts of 1-phenyl-4-amino-6-mercaptopyridazinium chloride in 100 parts of toluene is stirred with 2.5 parts of benzyl chloride for 1 hour at 110° C. 6.2 parts (90.2% of theory) of 1-phenyl-4-amino-6-benzylmercaptopyridazinium chloride is obtained; C17H16N3SCl, melting point 226° to 228° C after having been recrystallized from alcohol. The perchlorate melts at 170° to 171° C.

Sources & evidence

ORD record
ord-6e4f105c418647cc8673c521ce32e8cb
Source dataset
uspto-grants-1977_03
Patent number
US04011220

Reaction notes

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