HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Bicarbonate → HCID 21449852, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Bicarbonate | HCID 516892 | — |
| Reactant | HCID 21449727 | HCID 21449727 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Nickel | HCID 935 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 21449852 | HCID 21449852 | 76.8% |
Reaction Steps
32 parts of 1-phenyl-4,6-diamino-5-chloropyridazinium perchlorate in 200 parts of water in a stirred autoclave is stirred with 10 parts of sodium bicarbonate and 2 parts of Raney nickel for 3 hours at 100° C and 200 atmospheres gauge of hydrogen pressure. The discharge is filtered free from nickel and 20 parts of a 70% by weight perchloric acid is added to it. 22 parts (76.8% of theory) of 1-phenyl-4,6-diaminopyridazinium perchlorate is obtained; C10H11O4N4Cl, melting point 105° to 107° C after having been recrystallized from water.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04011220 |
| Source dataset | uspto-grants-1977_03 |
| ORD ID | ord-81b26dd1d0584fa69f5803a44e80acd4 |
| Source note | uspto-grants-1977_03 |