Beta-Nitrostyrene → alpha-(Nitromethyl)benzyl diethyldithiocarbamate

HRID 596500Notes

Reaction equation

HRID 596500 reaction equation
[N+:1]([CH:4]=[CH:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)([O-:3])=[O:2].[CH2:12]([N:14]([CH2:18][CH3:19])[C:15](=[S:17])[S-:16])[CH3:13].C([NH2+]CC)C>C(=S)=S>[CH2:12]([N:14]([CH2:18][CH3:19])[C:15](=[S:16])[S:17][CH:5]([CH2:4][N+:1]([O-:3])=[O:2])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH3:13]

Participants

4

Reactant 2

HCID 7626Beta-NitrostyreneHCID 2735004Diethylammonium diethylcarbamodithioate

Product 1

HCID 21324593alpha-(Nitromethyl)benzyl diethyldithiocarbamate

Reagents, catalysts & solvents 1

HCID 6348Carbon DisulfideSolvent

Procedure

As in Example 17, reaction of β-nitrostyrene with diethylammonium diethyldithiocarbamate in the presence of carbon disulfide gave α-(nitromethyl)benzyl diethyldithiocarbamate melting at 81° C.-82.5° C. when recrystallized without heating from acetone-2-propanol solution.

Sources & evidence

ORD record
ord-10ba8499b0cd4dbb99244d13c98d5429
Source dataset
uspto-grants-1977_03
Patent number
US04011230

Reaction notes

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