HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethyldithiocarbamic acid, dimethylamine → 2-Acetoxy-3-methoxy-alpha-(nitromethyl)benzyl dimethyldithiocarbamate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethyldithiocarbamic acid, dimethylamine | HCID 11728 | — |
| Reactant | 2-Methoxy-6-(2-nitrovinyl)phenyl acetate | HCID 53678486 | — |
| Solvent | Carbon Disulfide | HCID 6348 | — |
| Product | 2-Acetoxy-3-methoxy-alpha-(nitromethyl)benzyl dimethyldithiocarbamate | HCID 21324608 | — |
Reaction Steps
As in Example 17, reaction of 2-methoxy-6-(2-nitrovinyl)phenyl acetate from Example 22 with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave 2-acetoxy-3-methoxy-α-(nitromethyl)benzyl dimethyldithiocarbamate melting at 124° C.-125.5° C. after recrystallization without heating from dimethylformamide-methanol solution.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04011230 |
| Source dataset | uspto-grants-1977_03 |
| ORD ID | ord-8c66c30edbf14d77b59d66c8ed634224 |
| Source note | uspto-grants-1977_03 |