Dimethyldithiocarbamic acid, dimethylamine → HCID 21324611, compound

HRID 596507Notes

Reaction equation

HRID 596507 reaction equation
[Cl:1][C:2]1[CH:12]=[CH:11][CH:10]=[CH:9][C:3]=1[CH:4]=[CH:5][N+:6]([O-:8])=[O:7].[CH3:13][N:14]([CH3:18])[C:15](=[S:17])[S-:16].C[NH2+]C>C(=S)=S>[CH3:13][N:14]([CH3:18])[C:15](=[S:16])[S:17][CH:4]([CH2:5][N+:6]([O-:8])=[O:7])[C:3]1[CH:9]=[CH:10][CH:11]=[CH:12][C:2]=1[Cl:1]

Participants

4

Reactant 2

HCID 11728Dimethyldithiocarbamic acid, dimethylamineHCID 98458o-Chloro-beta-nitrostyrene

Product 1

HCID 21324611HCID 21324611, compound

Reagents, catalysts & solvents 1

HCID 6348Carbon DisulfideSolvent

Procedure

As in Example 17, reaction of o-chloro-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave o-chloro-α-(nitromethyl)benzyl dimethyldithiocarbamate melting at 102° C.-103.5° C. when recrystallized without heating from acetone-methanol solution.

Sources & evidence

ORD record
ord-418d3a9761f74f1e9c85d85d296027a6
Source dataset
uspto-grants-1977_03
Patent number
US04011230

Reaction notes

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