Dimethyldithiocarbamic acid, dimethylamine → HCID 21324615, compound

HRID 596510Notes

Reaction equation

HRID 596510 reaction equation
[Br:1][C:2]1[CH:12]=[CH:11][C:5]([CH:6]=[CH:7][N+:8]([O-:10])=[O:9])=[CH:4][CH:3]=1.[CH3:13][N:14]([CH3:18])[C:15](=[S:17])[S-:16].C[NH2+]C>C(=S)=S>[CH3:13][N:14]([CH3:18])[C:15](=[S:16])[S:17][CH:6]([CH2:7][N+:8]([O-:10])=[O:9])[C:5]1[CH:11]=[CH:12][C:2]([Br:1])=[CH:3][CH:4]=1

Participants

4

Reactant 2

HCID 11728Dimethyldithiocarbamic acid, dimethylamineHCID 274841HCID 274841, compound

Product 1

HCID 21324615HCID 21324615, compound

Reagents, catalysts & solvents 1

HCID 6348Carbon DisulfideSolvent

Procedure

As in Example 17, reaction of p-bromo-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave p-bromo-α-(nitromethyl)benzyl dimethyldithiocarbamate melting at 79° C.-81° C. when recrystallized without heating from acetone-ethanol solution.

Sources & evidence

ORD record
ord-55c38c5f731244d0a807bc08becc227b
Source dataset
uspto-grants-1977_03
Patent number
US04011230

Reaction notes

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