Dimethyldithiocarbamic acid, dimethylamine → alpha-(Nitromethyl)furfuryl dimethyldithiocarbamate

HRID 596511Notes

Reaction equation

HRID 596511 reaction equation
[N+:1]([CH:4]=[CH:5][C:6]1[O:7][CH:8]=[CH:9][CH:10]=1)([O-:3])=[O:2].[CH3:11][N:12]([CH3:16])[C:13](=[S:15])[S-:14].C[NH2+]C>C(=S)=S>[CH3:11][N:12]([CH3:16])[C:13](=[S:14])[S:15][CH:5]([CH2:4][N+:1]([O-:3])=[O:2])[C:6]1[O:7][CH:8]=[CH:9][CH:10]=1

Participants

4

Reactant 2

HCID 11728Dimethyldithiocarbamic acid, dimethylamineHCID 12781Furan, 2-[(1E)-2-nitroethenyl]-

Product 1

HCID 21324594alpha-(Nitromethyl)furfuryl dimethyldithiocarbamate

Reagents, catalysts & solvents 1

HCID 6348Carbon DisulfideSolvent

Procedure

As in Example 17, reaction of 2-(2-nitrovinyl)furan with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave α-(nitromethyl)furfuryl dimethyldithiocarbamate melting at 67° C.-68° C. after recrystallization from methanol.

Sources & evidence

ORD record
ord-1d86ee2c134849508e81897d8edcac89
Source dataset
uspto-grants-1977_03
Patent number
US04011230

Reaction notes

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