HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethyldithiocarbamic acid, dimethylamine → 5-Chloro-alpha-(nitromethyl)-2-thenyl dimethyldithiocarbamate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethyldithiocarbamic acid, dimethylamine | HCID 11728 | — |
| Reactant | HCID 818880 | HCID 818880 | — |
| Solvent | Carbon Disulfide | HCID 6348 | — |
| Product | 5-Chloro-alpha-(nitromethyl)-2-thenyl dimethyldithiocarbamate | HCID 21324591 | — |
Reaction Steps
As in Example 17, reaction of 2-chloro-5-(2-nitrovinyl)thiophene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave 5-chloro-α-(nitromethyl)-2-thenyl dimethyldithiocarbamate melting at 76° C.-77° C., after recrystallization without heating from acetone-methanol solution.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04011230 |
| Source dataset | uspto-grants-1977_03 |
| ORD ID | ord-a3f155a008a74666b20ef1fb4b5cc96a |
| Source note | uspto-grants-1977_03 |