HuagongsheHuagongshe Chemistry Print Report · For research reference only
Chloroform → 2-chloroformyl-5-oxo-5H-dibenzo[a,d]cycloheptene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Chloroform | HCID 6212 | — |
| Reactant | Thionyl Chloride | HCID 24386 | — |
| Reactant | 2-carboxy-5-oxo-5H-dibenzo[a,d]cycloheptene | HCID 12563001 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 2-chloroformyl-5-oxo-5H-dibenzo[a,d]cycloheptene | HCID 20310684 | — |
Reaction Steps
22 G. of 5-oxo-5H-dibenzo[a,d]cycloheptene-2-carboxylic acid is stirred in 200 ml. of chloroform, 50 ml. of thionyl chloride and 1 ml. of dimethylformamide for 8 hours. The mixture is evaporated to dryness and the residue recrystallized from acetonitrile to yield 2-chloroformyl-5-oxo-5H-dibenzo[a,d]cycloheptene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04011241 |
| Source dataset | uspto-grants-1977_03 |
| ORD ID | ord-2a2911dae3394d3386b2cd7ac4787123 |
| Source note | uspto-grants-1977_03 |