HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → 4-[(3-Chloropropyl)sulfanyl]benzene-1,2-diamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | Sodium Dithionite | HCID 24489 | — |
| Reactant | 4-[(3-Chloropropyl)sulfanyl]-2-nitroaniline | HCID 21450208 | — |
| Solvent | Water | HCID 962 | — |
| Product | 4-[(3-Chloropropyl)sulfanyl]benzene-1,2-diamine | HCID 21450210 | — |
Reaction Steps
6 G of 2nitro-4-(3-chloropropylthio)aniline is treated in 120 ml. methanol and 120 ml. of water with 30 g. of sodium hydrosulfite (Na2S2O4) on the steam bath for about 5 minutes. The reaction mixture is concentrated under vacuum and extracted well with chloroform. Evaporation of the dried extract affords 1,2-diamino-4-(3-chloropropylthio)benzene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04011320 |
| Source dataset | uspto-grants-1977_03 |
| ORD ID | ord-ae91a47ac2e34020b8af3ac2ce5a04d6 |
| Source note | uspto-grants-1977_03 |