HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium hydride → 2-Chlorobenzaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | Trimethylsulfonium iodide | HCID 75127 | — |
| Reactant | 2-(2-Chlorophenyl)oxirane | HCID 560709 | — |
| Product | 2-Chlorobenzaldehyde | HCID 6996 | — |
Reaction Steps
Following the procedure of Example 13 and employing 42.0 g. of 57% dispersion of sodium hydride in mineral oil, 200 g. (1.0 mol) of trimethylsulfonium iodide and 70.4 g. (0.50 mol) of o-chlorobenzaldehyde there is obtained o-chlorostyrene oxide.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04011319 |
| Source dataset | uspto-grants-1977_03 |
| ORD ID | ord-beb67e0f6ff94006b7db05a50c6e3875 |
| Source note | uspto-grants-1977_03 |