HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Bromohexadecane → 2-(Hexadecyloxy)thiophene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Bromohexadecane | HCID 8213 | — |
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | 2(5H)-Thiophenone | HCID 137898 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 2-(Hexadecyloxy)thiophene | HCID 21441827 | — |
Reaction Steps
A mixture of 20 g (0.2 mole) of 3-thiolen-2-one[R. T. Hawkins, J. Heterocyclic Chemistry 11, 291-4 (1974)], 61.1 g (0.2 mole) of 1-bromohexadecane, and 9.6 g (0.2 mole) of sodium hydride (50% in oil) in dry benzene is refluxed with stirring for 24 hours after which the solvent is removed and the product is distilled to give 2-hexadecyloxythiophene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04011334 |
| Source dataset | uspto-grants-1977_03 |
| ORD ID | ord-e481813421f9402eae647a485367f897 |
| Source note | uspto-grants-1977_03 |