HCID 20370064, compound → HCID 20370068, compound

HRID 596712Notes

Reaction equation

HRID 596712 reaction equation
FC1C=CC(C(C)(C)CC(Cl)=O)=CC=1.ClC1C=CC(C(C)(C)CC(Cl)=O)=CC=1.[Cl:29][C:30]1[CH:35]=[CH:34][C:33]([C:36]([CH3:47])([CH3:46])[CH:37]=[C:38]=[C:39]([CH3:45])[C:40]([O:42]CC)=[O:41])=[CH:32][CH:31]=1>>[Cl:29][C:30]1[CH:31]=[CH:32][C:33]([C:36]([CH3:47])([CH3:46])[CH:37]=[C:38]=[C:39]([CH3:45])[C:40]([OH:42])=[O:41])=[CH:34][CH:35]=1

Participants

4

Reactant 3

HCID 20370064HCID 20370064, compoundHCID 20370084HCID 20370084, compoundHCID 23293596HCID 23293596, compound

Product 1

HCID 20370068HCID 20370068, compound

Procedure

Repeating the procedure of Example 7, but replacing the 3-(p-fluorophenyl)-3-methyl-butyryl chloride used therein with an approximately equivalent amount of 3-(p-chlorophenyl)-3-methyl-butyryl chloride, there is accordingly obtained ethyl 5-(p-chlorophenyl)-2,5-dimethyl-hexa-2,3-dienoate from which is obtained 5-(p-chlorophenyl)-2,5-dimethyl-hexa-2,3-dienoic acid (m.p. 106° - 107.5°).

Sources & evidence

ORD record
ord-e229c498288f4c0595a6ecbc597b0472
Source dataset
uspto-grants-1977_03
Patent number
US04011339

Reaction notes

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