Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Acrylonitrile | HCID 7855 | — |
| Reactant | 1,4-Bis(trimethylsilyl)-1,4-dihydroquinoline | HCID 14892885 | — |
| Product | HCID 21446967 | HCID 21446967 | 73.6% |
Reaction Steps
A mixture consisting of 27.5 g (0.1 mol) of 1,4-bis-(trimethylsilyl)-1,4-dihydroquinoline and 6 g (0.1 mol) of acrylonitrile is heated in an inert atmosphere at 100°C for 150 hours. Fractional distillation yields 24.2 g (72%) of 1,4-bis-(trimethylsilyl)-2-(1-cyanoethyl)-1,2-dihydroquinoline: yellow-green oil, b.p. 106°-108°C/0.001 mm.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04013661 |
|---|
| Source dataset | uspto-grants-1977_03 |
|---|
| ORD ID | ord-347bc777635c473eb50aeb21ca8c40b9 |
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| Source note | uspto-grants-1977_03 |
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