Sulfuryl chloride → HCID 70638139, compound

HRID 597291Notes

Reaction equation

HRID 597291 reaction equation
[C:1]1([C:7]2[CH:15]=[C:11]3[CH:12]=[CH:13][CH:14]=[C:10]3[O:9][C:8]=2[CH2:16][C:17]([OH:19])=[O:18])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.S(Cl)([Cl:23])(=O)=O>C1C=CC=CC=1>[Cl:23][C:8]1([CH2:16][C:17]([OH:19])=[O:18])[CH:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)[CH:15]=[C:11]2[CH:12]=[CH:13][CH:14]=[C:10]2[O:9]1

Participants

4

Reactant 2

HCID 24648Sulfuryl chlorideHCID 70609976HCID 70609976, compound

Product 1

HCID 70638139HCID 70638139, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

3-Phenyl-7-benzofuranacetic acid, 6.0 g., is heated for 15 minutes with 3.4 g. of sulfuryl chloride in 50 ml. of benzene then left at room temperature overnight to give 2-chloro-3-phenyl-7-benzofuranacetic acid which precipitates from the reaction mixture. Recrystallization from benzene-hexane gives material of m.p. 150.5°-152° C.

Workup

  1. temperature, is heated for 15 minutes with 3.4 g

Sources & evidence

ORD record
ord-ce9d1655652b4744ba0a3405879b6c54
Source dataset
uspto-grants-1977_03
Patent number
US04013692

Reaction notes

Loading…