1,1-Bis(methylthio)-2-nitroethylene → HCID 70546477, compound

HRID 597401Notes

Reaction equation

HRID 597401 reaction equation
[NH2:1][CH2:2][CH2:3][CH2:4][S:5][C:6]1[NH:7][CH:8]=[CH:9][N:10]=1.[N+:11]([CH:14]=[C:15](SC)[S:16][CH3:17])([O-:13])=[O:12]>>[N+:11]([CH:14]=[C:15]([S:16][CH3:17])[NH:1][CH2:2][CH2:3][CH2:4][S:5][C:6]1[NH:7][CH:8]=[CH:9][N:10]=1)([O-:13])=[O:12]

Participants

3

Reactant 2

HCID 836231,1-Bis(methylthio)-2-nitroethyleneHCID 12923401HCID 12923401, compound

Product 1

HCID 70546477HCID 70546477, compound

Procedure

By the procedure of Example 8 (i), 2-(3-aminopropylthio)-imidazole (from the dihydrobromide (3.8 g)) is reacted with 1-nitro-2,2-bis-methylthioethylene (2.0 g) to give 1-nitro-2-methylthio-2-[3-(2-imidazolylthio)propylamino]ethylene which, on treatment with 2-[(2-aminoethyl)thiomethyl]-3-chloropyridine by the procedure of Example 1 (a) (ii) yields the title compound.

Sources & evidence

ORD record
ord-4f8b170188c8450ab65acc80fe87650e
Source dataset
uspto-grants-1977_03
Patent number
US04013769

Reaction notes

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