1,1-Bis(methylthio)-2-nitroethylene → 1-Nitro-2-methylthio-2-[2-((2-amino-5-1,3,4-thiadiazolyl)methylthio)ethylamino]ethylene

HRID 597416Notes

Reaction equation

HRID 597416 reaction equation
[NH2:1][C:2]1[S:3][C:4]([CH2:7][S:8][CH2:9][CH2:10][NH2:11])=[N:5][N:6]=1.[N+:12]([CH:15]=[C:16](SC)[S:17][CH3:18])([O-:14])=[O:13]>>[N+:12]([CH:15]=[C:16]([S:17][CH3:18])[NH:11][CH2:10][CH2:9][S:8][CH2:7][C:4]1[S:3][C:2]([NH2:1])=[N:6][N:5]=1)([O-:14])=[O:13]

Participants

3

Reactant 2

HCID 836231,1-Bis(methylthio)-2-nitroethyleneHCID 129234182-Amino-5-(2-aminoethyl)thiomethyl-1,3,4-thiadiazole

Product 1

HCID 705428991-Nitro-2-methylthio-2-[2-((2-amino-5-1,3,4-thiadiazolyl)methylthio)ethylamino]ethylene

Procedure

By the procedure of Example 8(i), 2-amino-5-(2-aminoethyl)thiomethyl-1,3,4-thiadiazole (from the dihydrobromide) is reacted with 1-nitro-2-,2-bis-methylthioethylene to give 1-nitro-2-methylthio-2-[2-((2-amino-5-1,3,4-thiadiazolyl)-methylthio)ethylamino]ethylene.

Sources & evidence

ORD record
ord-b93e37a55022444bb14965532409da19
Source dataset
uspto-grants-1977_03
Patent number
US04013769

Reaction notes

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