2-(Bis(methylsulfanyl)methylidene)propanedinitrile → 1,1-Dicyano-2-methylthio-2-[2-((3-chloro-2-pyridyl)methylthio)ethylamino]ethylene

HRID 597418Notes

Reaction equation

HRID 597418 reaction equation
[NH2:1][CH2:2][CH2:3][S:4][CH2:5][C:6]1[C:11]([Cl:12])=[CH:10][CH:9]=[CH:8][N:7]=1.[C:13]([C:15]([C:21]#[N:22])=[C:16](SC)[S:17][CH3:18])#[N:14]>>[C:13]([C:15]([C:21]#[N:22])=[C:16]([S:17][CH3:18])[NH:1][CH2:2][CH2:3][S:4][CH2:5][C:6]1[C:11]([Cl:12])=[CH:10][CH:9]=[CH:8][N:7]=1)#[N:14]

Participants

3

Reactant 2

HCID 992292-(Bis(methylsulfanyl)methylidene)propanedinitrileHCID 129515322-(3-Chloropyrid-2-ylmethylthio)ethylamine

Product 1

HCID 203627951,1-Dicyano-2-methylthio-2-[2-((3-chloro-2-pyridyl)methylthio)ethylamino]ethylene

Procedure

Reaction of 2-[(2-aminoethyl)thiomethyl]-3-chloropyridine with 1,1-dicyano-2,2-bis-methylthioethylene by the procedure of Example 1(b)(i) yields 1,1-dicyano-2-methylthio-2-[ 2-((3-chloro-2-pyridyl)methylthio)ethylamino]-ethylene.

Sources & evidence

ORD record
ord-c399d8ae94a94d2e94952961ef7a3caf
Source dataset
uspto-grants-1977_03
Patent number
US04013769

Reaction notes

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