Benzene, [[2,2-bis(methylthio)ethenyl]sulfonyl]- → 1-Benzenesulphonyl-2-methylthio-2-[2-((3-chloro-2-pyridyl)methylthio)ethylamino]ethylene

HRID 597420Notes

Reaction equation

HRID 597420 reaction equation
[NH2:1][CH2:2][CH2:3][S:4][CH2:5][C:6]1[C:11]([Cl:12])=[CH:10][CH:9]=[CH:8][N:7]=1.[C:13]1([S:19]([CH:22]=[C:23](SC)[S:24][CH3:25])(=[O:21])=[O:20])[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1>>[C:13]1([S:19]([CH:22]=[C:23]([S:24][CH3:25])[NH:1][CH2:2][CH2:3][S:4][CH2:5][C:6]2[C:11]([Cl:12])=[CH:10][CH:9]=[CH:8][N:7]=2)(=[O:21])=[O:20])[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=1

Participants

3

Reactant 2

HCID 12296879Benzene, [[2,2-bis(methylthio)ethenyl]sulfonyl]-HCID 129515322-(3-Chloropyrid-2-ylmethylthio)ethylamine

Product 1

HCID 706243461-Benzenesulphonyl-2-methylthio-2-[2-((3-chloro-2-pyridyl)methylthio)ethylamino]ethylene

Procedure

Reaction of 2-[(2-aminoethyl)thiomethyl]-3-chloropyridine with 1-benzenesulphonyl-2,2-bis-methylthioethylene by the procedure of Example 1(b)(i) yields 1-benzenesulphonyl-2-methylthio-2-{2-[(3-chloro-2-pyridyl)methylthio]ethylamino}-ethylene.

Sources & evidence

ORD record
ord-ba807ea2af144d06a63df8f9c128a329
Source dataset
uspto-grants-1977_03
Patent number
US04013769

Reaction notes

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