Diazomethane → HCID 86734576, compound

HRID 597449Notes

Reaction equation

HRID 597449 reaction equation
[CH3:1][CH:2]([C:12]([CH3:14])=[O:13])[C:3]([NH:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)=[S:4].[N+](=[CH2:17])=[N-]>>[CH3:17][O:13]/[C:12](/[CH3:14])=[C:2](/[CH3:1])\[C:3]([NH:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)=[S:4]

Participants

3

Reactant 2

HCID 9550DiazomethaneHCID 86734577HCID 86734577, compound

Product 1

HCID 86734576HCID 86734576, compound

Procedure

2-methylthioacetoacetanilide [formed from α-chloroacetoacetanilide and sodium methylmercaptan] was reacted with diazomethane to obtain 3-methoxy-2-methylthio-crotonanilide melting at 155° C.

Sources & evidence

ORD record
ord-972c456d1ec84d19b574469684bb2471
Source dataset
uspto-grants-1977_03
Patent number
US04014679

Reaction notes

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