Ethanol → HCID 86734585, compound

HRID 597490Notes

Reaction equation

HRID 597490 reaction equation
[CH2:1]([N:3]([CH2:13][CH:14]([C:19]1[S:20][C:21]2[CH:27]=[CH:26][CH:25]=[CH:24][C:22]=2[N:23]=1)[O:15][C:16](=[S:18])[CH3:17])[C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([N+:10]([O-])=O)[CH:5]=1)[CH3:2].[CH2:28]([OH:30])[CH3:29]>C(OC(=O)C)(=O)C.[Pd]>[CH2:1]([N:3]([CH2:13][CH:14]([C:19]1[S:20][C:21]2[CH:27]=[CH:26][CH:25]=[CH:24][C:22]=2[N:23]=1)[O:15][C:16](=[S:18])[CH3:17])[C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([NH:10][C:28](=[O:30])[CH3:29])[CH:5]=1)[CH3:2]

Participants

5

Reactant 2

HCID 702EthanolHCID 86734586HCID 86734586, compound

Product 1

HCID 86734585HCID 86734585, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 7918Acetic AnhydrideSolvent

Procedure

4.17 Parts of N-ethyl-N-(benzthiazolyl-2-thioacetoxyethyl)m-nitroaniline are dissolved in 75 parts of absolute ethanol and 25 parts of acetic anhydride and hydrogenated at 45° using 10% Pd/C as catalyst. The catalyst is filtered off and worked up in the usual manner to furnish N-ethyl-N-(benzthiazolyl-2-thio acetoxyethyl) m-acetamido aniline having the formula ##STR22##

Workup

  1. filtrationThe catalyst is filtered off

Sources & evidence

ORD record
ord-a1082607140d438aa99f9cc570e42df4
Source dataset
uspto-grants-1977_03
Patent number
US04014864

Reaction notes

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