Ammonia → Ammonium Chloride

HRID 597602Notes

Reaction equation

HRID 597602 reaction equation
[CH3:1][CH2:2][CH2:3][CH2:4][O-:5].[CH3:6][CH2:7][CH2:8][CH2:9][O-:10].[CH3:11][CH2:12][CH2:13][CH2:14][O-:15].[OH2:16].[V:17].O=[V].[ClH:20].Cl.Cl.[NH3:23]>C(O)CCC>[CH3:1][CH2:2][CH2:3][CH2:4][O-:5].[CH3:6][CH2:7][CH2:8][CH2:9][O-:10].[CH3:11][CH2:12][CH2:13][CH2:14][O-:15].[OH2:16].[V:17].[Cl-:20].[NH4+:23]

Participants

6

Reactant 3

HCID 222AmmoniaHCID 24410Vanadium trichloride oxideHCID 100974852HCID 100974852, compound

Product 2

HCID 25517Ammonium ChlorideHCID 100974852HCID 100974852, compound

Reagents, catalysts & solvents 1

HCID 2631-ButanolSolvent

Procedure

Vanadates, such as butyl vanadate, have been prepared by reacting vanadium oxytrichloride with an excess of butyl alcohol in the presence of ammonia to form butyl vanadate and ammonium chloride. The butyl vanadate solution was separated from the ammonium chloride crystals by filtration. However, since the crystalline ammonium chloride has a tendency to plug the filter, it is difficult to filter off the butyl vanadate. Moreover, the filtration step must be conducted in a closed system to prevent hydrolysis of the butyl vanadate, thus resulting in an expensive process.

Sources & evidence

ORD record
ord-12fb45601e564dfd92ac608eabf55df6
Source dataset
uspto-grants-1977_03
Patent number
US04014912

Reaction notes

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