Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Hydrazinecarboxylic acid, ethyl ester | HCID 20064 | — |
| Reactant | HCID 11444535 | HCID 11444535 | — |
| Catalyst | Acetic Acid | HCID 176 | — |
| Product | HCID 76550040 | HCID 76550040 | — |
Reaction Steps
Compound 30 (44 mg, 0.077 mmol) was dissolved in EtOH (1 mL) and hydrazinecarboxylic acid ethyl ester (24 mg, 0.231 mmol) and 1 drop of AcOH were added. The reaction mixture was stirred at 120° C. for 15 hrs, after which the crude mixture was purified by LC/MS. The isomers separated and the desired isomer was taken on into the next step. Calculated mass=660. Observed mass=660.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US07897599B2 |
|---|
| Source dataset | uspto-grants-2011_03 |
|---|
| ORD ID | ord-3ddae00e9d0b48ecb3c3cbbfc48a92af |
|---|
| Source note | uspto-grants-2011_03 |
|---|
